Study of the Interaction Mechanism in the Biosorption of Copper(II) Ions onto Posidonia oceanica and Peat     

Marta Izquierdo  Paula Marzal  Carmen Gabaldón  Margherita Silvetti  Paola Castaldi 《洁净——土壤、空气、水》2012,40(4):428-437

A systematic approach was used to characterize the biosorption of copper(II) onto two biosorbents, Posidonia oceanica and peat, focusing on the interaction mechanisms, the copper(II) sorption–desorption process and the thermal behavior of the biosorbents. Sorption isotherms at pH 4–6 were obtained and the experimental data were fitted to the Langmuir model with a maximum uptake (q_max) at pH 6 of 85.78 and 49.69 mg g^?1, for P. oceanica and peat, respectively. A sequential desorption (SD) with water, Ca(NO₃)₂, and EDTA was applied to copper‐saturated biosorbents. Around 65–70% copper(II) were desorbed with EDTA, indicating that this heavy metal was strongly bound. The reversibility of copper(II) sorption was obtained by desorption with HCl and SD. Fourier transform IR spectroscopy (FTIR) analysis detected the presence of peaks associated with OH groups in aromatic and aliphatic structures, CH, CH₂, and CH₃ in aliphatic structures, COO^? and COOH groups and unsaturated aromatic structures on the surface of both biosorbents, as well as peaks corresponding to Si? O groups on the surface of peat. The results of SEM‐EDX and FTIR analysis of copper‐saturated samples demonstrated that ion exchange was one of the mechanisms involved in copper(II) retention. Thermal analysis of biosorbent samples showed that copper(II) sorption–desorption processes affected the thermal stability of the biosorbents.  相似文献   

基于格点降水场的中国东部冬季降水变化特征   总被引：1，自引：0，他引：1  

廖荣伟  沈艳  张冬斌 《气象与环境学报》2013,29(5):55-62

采用1958-2007年国家级2419地面台站0.5°×0.5°格点降水场和NCEP/NCAR月平均再分析资料,对中国东部冬季降水量变化及对应的大气环流变化特征进行研究。结果表明：冬季近50 a降水量时间序列表现出明显的长期气候变化趋势。20世纪90年代降水较多,大气水汽充足, 60、70年代相反,这种特征反映出水汽在东亚地区输送的强弱及从海洋输入中国大陆水汽的多寡。降水量强弱年差值合成的异常降水量可达40 mm以上。降水量与水汽收支时间序列的相关系数为0.605。水汽收支与降水场的回归系数揭示了长江流域以南地区为异常大值区。降水量强年,冬季风偏弱,对流层低层和高层为异常气旋式环流,低层盛行异常偏南风,孟加拉湾、南海异常暖湿水汽输送到中国东部地区,中国东部近海海温偏高,配合加强的异常垂直上升运动,有利于水汽的增加,造成降水量增加。  相似文献   

中国东部夏季持续性降水日变化在淮河南北的差异分析   总被引：8，自引：0，他引：8       下载免费PDF全文

原韦华  宇如聪  傅云飞 《地球物理学报》2014,57(3):752-759

本文利用1961-2006年我国285站观测的逐时降水数据,分析了中国东部不同地区夏季平均降水日变化随降水持续时间的变化特征. 虽然整个东部地区都表现为短时降水峰值较一致地出现在下午17时左右,持续较长时间降水在清晨前后发生峰值降水,但持续性降水日变化的平均峰值时间以淮河为界存在显著南北差异. 北部地区的持续性降水峰值主要出现在02-06时前后;南部地区的持续性降水峰值时间出现在06-10时. 无论是降水强度或频次的日变化峰值的南北差异均较明显,但降水强度差异更为突出,且主要表现在持续性强降水中. 进一步分析发现：一方面北部地区持续性强降水开始时间较南部地区更早;另一方面,北部地区降水从开始到峰值经历的时间更短. 最后,对持续性强降水峰值时间南北差异的可能原因进行了初步讨论.  相似文献   

Provenance discrimination and Source-to-Sink studies from a dryland fluvial regime： An example from Kachchh,western India     

S. P. PRIZOMWALA  Nilesh BHATT  N. BASAVAIAH 《国际泥沙研究》2014,29(1):99-109

Tracing the sediment delivery from its source terrain to its ultimate sink envisage multiple factors that play a vital role in understanding present day erosional engine.To accomplish this,it is significant to distinguish the variable end-members contributing to the basin.The findings from the study of dryland coastal fluvial regime in Kachchh(Western India),which is one of the end members contributing to the Gulf of Kachchh coast(partial sink) and finally to the Arabian Sea(ultimate sink) have been presented here.Multi-proxy sediment provenance proxies such as grain-size,clay minerals,geochemistry and magnetic minerals have been employed to evaluate the provenance discriminating characteristics of the Kachchh dryland fluvial system and factors influencing them.The results of different proxies indicate that the provenance signatures of uplands are quite characteristic with magnetic susceptibility(χ) values of 20×10~(-7)m~3kg~(-1) and smectite(S)/kaolinite(K) ratio between 0.26 and 0.49.The middle reaches show marked increase in magnetic mineral concentration with χ values(140×10~(-7)m~3kg~(-1))and S/K ratio(4.92),while the estuarine tract shows χ values(80×10~(-7)m~3kg~(-1)),S/K ratio(1.90) and,characteristic heavy minerals(i.e.mica minerals),probably reflect the interplay between land and sea oscillations.Major sources of sediments within catchment scale were identified,viz.,upland sedimentary rocks(Juran and Bhuj Formation sandstone-shale) and middle reaches volcanic(Deccan Trap Formation basalt) rocks.The present study draw cautions in provenance of sediment discrimination in areas influenced by Deccan basalt that has the overwhelming sediment delivery and a comparatively subdued effects of other provenance signatures.The studied proxies of mineralogy of clays,magnetic minerals and geochemistry of heavy and major elements serve as the potential for fingerprint of sediment source regions and hence behold a strong position in source to sink studies globally.  相似文献   

Distribution and source of heavy metals in the surface sediments from the near-shore area,north Jiangsu Province,China   总被引：1，自引：0，他引：1  

Gang Xu  Jian Liu  Shaofeng Pei  Xianghuai Kong  Gang Hu 《Marine pollution bulletin》2014

Samples of surface sediment and vibrocore were collected in the near-shore area of north Jiangsu Province for grain size, elements, ²¹⁰Pb_excess and ¹³⁷Cs analyses. In our study area, the diversity of metal concentration was controlled not by the grain size, but by the source. The element content of the old Yellow River Delta was used as baseline for our study area. Geoaccumulation indexes indicate that no station was polluted by Cu, Pb, Zn and As, but the I_geo values of As were close to zero in some stations. Slight pollution caused by Cd was observed in some stations. Correlation and enrichment factors suggest that Cu, Pb and Zn are lithogenic in origin, while As and Cd are mixed in origin. Especially, in some polluted stations Cd was obviously anthropogenic in origin.  相似文献   

Acute effects of heavy metals on the expression of glutathione-related antioxidant genes in the marine ciliate Euplotes crassus     

Se-Hun Kim  Se-Joo Kim  Jae-Seong Lee  Young-Mi Lee 《Marine pollution bulletin》2014

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Assessment of heavy metals/metalloid (As,Pb, Cd,Ni, Zn,Cr, Cu,Mn) concentrations in edible fish species tissue in the Pearl River Delta (PRD), China     

《Marine pollution bulletin》2014,78(1-2):235-245

The major aim of this study was to investigate heavy metal content of edible fish in the PRD. Eleven species of fish (consisting of 711 individuals) [catfish (Clarias fuscus), tilapia (Oreochromis mossambicus), grass carp (Ctenopharyngodon idellus), bighead carp (Aristichthys nobilis), mandarin fish (Siniperca kneri), snakehead (Channa asiatiea), black bass (Micropterus salmoides), mangrove snapper (Lutjanus griseus), star snapper (Lutjanu stellatus), snubnose pompano (Trachinotus blochii) and orange-spotted grouper (Epinephelus coioides)] were collected for the analyses of heavy metals. Overall concentrations (mg/kg, ww) in the fish muscles were: As (0.03–1.53), Pb (0.03–8.62), Cd (0.02–0.06), Ni (0.44–9.75), Zn (15.7–29.5), Cr (0.22–0.65), Cu (0.79–2.26), Mn (0.82–6.91). Significant level of Pb were found in tilapia at all locations. It is recommended that heavy metal concentrations in different fish species must be determined on a regular basis in the future so as to reduce human health risks from acute and chronic food intoxication.  相似文献   

Anthropogenic lead concentrations and sources in Baltic Sea sediments based on lead isotopic composition     

Agata Zaborska 《Marine pollution bulletin》2014

The Gulf of Gdańsk is influenced by heavy metals of anthropogenic origin. In this study, temporal concentration changes of Pb, Zn, Cd, and Cu were studied in six, 50 cm long sediment cores. The main aim of the study was to concentrate on the history of Pb fluxes and Pb isotopic composition (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) to trace Pb sources. The lowest Pb concentrations (19 μg g⁻¹) were measured in sediments deposited circa 1860, while the highest Pb concentrations (63–147 μg g⁻¹) were measured in sediments deposited between 1960s and 70s. Pre-industrial Pb fluxes were 7 Pb m² year⁻¹, while after WWII they reached 199 Pb m² year⁻¹. Highest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.22) were measured in the oldest sediment layers, and the lowest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.165) were measured in the sediments deposited in 1970s–90s. During the period of highest Pb contamination, the anthropogenic Pb fraction reached up to 93%. A general discussion of the Pb sources, emissions, and loads for Poland is included.  相似文献   

Biomonitoring of organochlorine compounds and trace metals along the Eastern Adriatic coast (Croatia) using Mytilus galloprovincialis     

Zorana Kljakovi?-Gašpi?  Snje?ana Herceg-Romani? 《Marine pollution bulletin》2010,60(10):1879-1889

The paper presents the results of monitoring trace organic contaminants (17 PCBs and 7 OCPs) and 6 trace metals (Cd, Cr, Cu, Hg, Pb and Zn) in the coastal waters of the eastern Adriatic in 2006 using Mytilus galloprovincialis as indicator species. OCPs were found in all samples (0.07-14.3 ng g⁻¹ d.wt.), while in positive samples concentrations of PCBs ranged between 0.16 and 20.5 ng g⁻¹ d.wt. The α-HCH/γ-HCH and DDE/DDT ratios indicated recent input of γ-HCH and DDT. Spatial distributions of HCB, PCBs, DDTs and Hg were significantly correlated with population density. Although elevated concentrations of all trace metals and organic contaminants were recorded in the densely populated and industrialized areas, overall data point to relatively low level of contamination of the eastern Adriatic coast. Evaluation of the risks to human health associated with consumption of the mussels suggested that there is no health risk for moderate shellfish consumers.  相似文献   

A point based Eulerian definition of rain event based on statistical properties of inter drop time intervals: An application to Chilbolton data     

Massimiliano Ignaccolo  Carlo De Michele 《Advances in water resources》2010

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